Bulg. J. Phys. vol.27 no.S1 (2000), pp. 169-172



The SnS2-SnSe2 System: Growth and Morphology

M.M. Gospodinov1, V. Marinova1, I. Yanchev2, A.N. Anagnostopoulos3, K. Kyritsi3
1Bulgarian Academy of Sciences, Solid State Physics Institute, Sofia 1784, Bulgaria
2Semiconductor Physics Dept. Faculty of Physics, St. Kliment Ohridski Univ., Sofia, Bulgaria
3Physics Dept, Aristotle Univ. of Thessaloniki, GR54006 Thessaloniki, Greece
Abstract. Large (SnS2)x-(SnSe2)1-x crystals were grown using the vertical Bridgman technique. The composition index x was varied from 0 to 1 (x=0.0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1.0). The colour of the crystals grown by this method was changing from orange-yellow to black with increasing x. They possessed a pronounced layered structure with the cleavage plane perpendicular to the c-crystallographic axis. A SEM-study combined with an EDAX analysis confirms these results.

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