Bulg. J. Phys. vol.23 no.3-4 (1996), pp. 162-169



The Oxygen Vacancies — Pseudo-Jahn-Teller Defect Centers in Quartz

M. Georgiev, A. Manov
G. Nadjakov Institute of Solid State Physics, Bulgarian Academy of Sciences, 72 Tzarigradsko Chaussee Blvd., 1784 Sofia, Bulgaria
Abstract. The pseudo-Jahn-Teller effect was applied for the description of the E'2, E'4 defect centers as well as for H- ion at E'4 defect center in alpha-quartz. The idea for the application of the pseudo-Jahn-Teller effect to defect centers' description is supported by new results. The physical essence of the pseudo-Jahn-Teller effect makes possible, in a natural way, the introduction of the characteristic large relaxations and charge transfers pertinent to the E'-defect centers. Considerations presented in this paper allow to conclude that the pseudo-Jahn-Teller effect leads to the establishment of E'-defect centers stable state.

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