Bulg. J. Phys. vol.40 no.4 (2013), pp. 294-300



Photosensitive Soft Matter: Mixtures of Nematic Liquid Crystal with Azo Molecules

A.G. Petrov1, I.G. Marinov1, G.B. Hadjichristov1, S. Sridevi2, U.S. Hiremath2, C.V. Yelamaggad2, S.K. Prasad2
1Institute of Solid State Physics, Bulgarian Academy of Sciences, 72 Tzarigradsko Chaussee Blvd., 1784 Sofia, Bulgaria
2Centre for Soft Matter Research, Jalahalli, Bangalore 560 013, India
Abstract. Photosensitive soft matter based upon guest-host liquid crystal systems was prepared by mixing azobenzene-containing mesogens with the nematic liquid crystal 4-butyl-cyclohexane carboxylic acid 4-pentyloxy-phenyl ester (CM80). Binary mixtures of the host CM80 with three azo-bonded compounds as UV-active dopants (guests) at a relatively small concentration of 1~wt.% were characterized by thermo-optical, dielectric, spectral and flexoelectric measurements. The study aimed to determine the mechanisms that result in variations of material parameters caused by light-driven molecular conformation change of the azo-dye guest molecules (the transition from rod-shaped trans isomers to bent-shaped cis isomers).

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